Effective voltammetric tool for Nano-detection of triazine herbicide (1-Chloro-3-ethylamino-5-isopropylamino-2,4,6-triazine) by naphthalene derivative

Singh, S and Narasimhappa, P and Khan, NA and Chauhan, V and Shehata, N and Behera, SK and Singh, J and Ramamurthy, PC (2023) Effective voltammetric tool for Nano-detection of triazine herbicide (1-Chloro-3-ethylamino-5-isopropylamino-2,4,6-triazine) by naphthalene derivative. In: Environmental Research, 236 .

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Abstract

The development and operation of a nanosensor for detecting the poisonous 1-chloro-3-ethylamino-5-isopropylamino-2,4,6-triazine (Atrazine) are described in this study for the first time. The carbon electrode (CE) surface was modified with cysteine-substituted naphthalene diimide to create this sensitive platform. The developed nanosensor (NDI-cys/GCE) was evaluated for its ability to sense Atrazine using differential pulse voltammetry and cyclic voltammetry. To achieve the best response from the target analyte, the effects of several parameters were examined to optimize the conditions. The cysteine-substituted naphthalene diimide significantly improved the signals of the Atrazine compared to bare GCE due to the synergistic activity of substituted naphthalene diimide and cysteine molecules. Under optimal conditions, atrazine detection limits at the (NDI-cys/GCE) were reported to be 94 nM with a linear range of 10�100 μM. The developed sensing platform also showed positive results when used to detect the atrazine herbicide in real tap water, wastewater, and milk samples. Furthermore, a reasonable recovery rate for real-time studies, repeatability, and stability revealed that the developed electrochemical platform could be used for sample analysis. © 2023 Elsevier Inc.

Item Type:	Journal Article
Publication:	Environmental Research
Publisher:	Academic Press Inc.
Additional Information:	The copyright for this article belongs to the Academic Press Inc.
Keywords:	Amino acids; Cyclic voltammetry; Electrodes; Nanosensors; Naphthalene; Nondestructive examination; Weed control, Carbon electrode; Development and operations; Electrochemicals; Electrode surfaces; Naphthalene derivatives; Naphthalene diimide; Real time analysis; Sensing; Triazine herbicides; Voltammetric, Herbicides
Department/Centre:	Division of Interdisciplinary Sciences > Interdisciplinary Centre for Water Research Division of Mechanical Sciences > Materials Engineering (formerly Metallurgy)
Date Deposited:	08 Nov 2023 08:06
Last Modified:	08 Nov 2023 08:06
URI:	https://eprints.iisc.ac.in/id/eprint/83019

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