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Design and synthesis of thieno3,4-cpyrrole-4,6-dione based conjugated copolymers for organic solar cells

Kotturappa, CG and Gopikrishna, MM and Rao, AD and Ramamurthy, PC (2017) Design and synthesis of thieno3,4-cpyrrole-4,6-dione based conjugated copolymers for organic solar cells. In: Polymer International, 66 (8). pp. 1206-1213.

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Official URL: https://doi.org/10.1002/pi.5377

Abstract

A new series of conjugated copolymers (PBDT-TPD, PBDT-Th-TPD, PBDT-TT-TPD) containing donor–acceptor (D − A) structure electron-rich benzo[1,2-b:4,5-b′ ]dithiophene (BDT) units with branched alkyl thiophene side chains and electron-deficient 5-(2-octyl)-4H-thieno[3,4-c]pyrrole-4,6(5H)-dione (TPD) units was designed and synthesized. To tune the optical and electrochemical properties of the copolymers, the conjugation length of the copolymers was extended by introducing

Item Type: Journal Article
Publication: Polymer International
Publisher: John Wiley and Sons Ltd
Additional Information: The copyright for this article belongs to John Wiley and Sons Ltd.
Keywords: Aromatic compounds; Cyclic voltammetry; Heterojunctions; Molecular orbitals; Organic solar cells; Polymer solar cells; Thiophene, Bulk heterojunction; Bulk heterojunction solar cells; Conjugated copolymers; Electron-deficient; Highest occupied molecular orbital energy levels; Power conversion efficiencies; Properties of the copolymers; Wavelength regions, Solar cells
Department/Centre: Division of Mechanical Sciences > Materials Engineering (formerly Metallurgy)
Date Deposited: 19 Jul 2022 05:30
Last Modified: 19 Jul 2022 05:30
URI: https://eprints.iisc.ac.in/id/eprint/74863

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