Conformation-Selective Self-Assembly of Pd6Trifacial Molecular Barrels Using a Tetrapyridyl Ligand

Howlader, P and Ahmed, S and Mondal, S and Zangrando, E and Mukherjee, PS (2022) Conformation-Selective Self-Assembly of Pd6Trifacial Molecular Barrels Using a Tetrapyridyl Ligand. In: Inorganic Chemistry, 61 (21). pp. 8121-8125.

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Abstract

A conformationally flexible tetrapyridyl ligand L was assembled separately with three cis-blocked 90° PdII acceptors (M1, M2, and M3) containing different blocking diamines. Surprisingly, different conformations of the donor L were arrested by the acceptors depending on the nature of the blocking amine, leading to the formation of isomeric Pd6 barrels (B1, B2, and B3). B2 and B3 with larger windows have been used to encapsulate polyaromatic hydrocarbons.

Item Type:	Journal Article
Publication:	Inorganic Chemistry
Publisher:	American Chemical Society
Additional Information:	The copyright for this article belongs to the American Chemical Society
Keywords:	Isomerism; Ligands; Molecular Conformation; Conformations; Ligands; ligand; Blockings; Polyaromatic hydrocarbons; conformation; isomerism; Self assembly
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	30 Jun 2022 09:50
Last Modified:	30 Jun 2022 09:50
URI:	https://eprints.iisc.ac.in/id/eprint/74095

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