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Tribophosphorescence from a Simple Boronic Ester

Prasad Nandi, R and Ghosh, S and Venkatasubbaiah, K and Kumbhar, D and Thilagar, P (2022) Tribophosphorescence from a Simple Boronic Ester. In: ChemPhotoChem .

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Official URL: https://doi.org/10.1002/cptc.202200026

Abstract

We demonstrate the room temperature tribophosphorescence from a simple anthracene boronic ester, 9-(pinacolboryl)anthracene (1). Both 1 and 9,10-bis(pinacolboryl)anthracene (2) show fluorescence and delayed emission at room temperature in the solid-state. Under mechanical stress, 1 displays tribophosphorescence. In contrast, 2 shows mechanofluorochromism under similar conditions. Detailed optical, computational, and crystal structural studies are carried out to rationalize the tribophosphorescence characteristics of 1. © 2022 Wiley-VCH GmbH.

Item Type: Journal Article
Publication: ChemPhotoChem
Publisher: John Wiley and Sons Inc
Additional Information: The copyright for this article belongs to John Wiley and Sons Inc.
Keywords: anthracene; boronic ester; mechanochromism; tribophosphorescence
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 06 Jun 2022 06:05
Last Modified: 06 Jun 2022 06:05
URI: https://eprints.iisc.ac.in/id/eprint/73143

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