Facile enantiospecific syntheses of oxabicyclo4.4.0]decene-diones from carvone via mild Lewis acid mediated lactonizations

Srikrishna, Adusumilli and Satyanarayana, Gedu (2019) Facile enantiospecific syntheses of oxabicyclo4.4.0]decene-diones from carvone via mild Lewis acid mediated lactonizations. In: INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 58 (3, B). pp. 362-370.

PDF Ind_J_Chem_58B_362-370_2019.pdf - Published Version Restricted to Registered users only Download (277kB) | Request a copy

Abstract

An efficient and concise enantiospecific syntheses of oxabicyclo4.4.0]decene-diones have been accomplished starting from carvone. This strategy is a chiron based approach by making use of mild Lewis acid mediated intramolecular lactonization as key step for the formation of fused bicyclic lactones. Notably, these bicyclic lactones constitute bicyclic carbon framework of diterpene natural products.

Item Type:	Journal Article
Publication:	INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY
Publisher:	NATL INST SCIENCE COMMUNICATION & INFORMATION RESOURCES-NISCAIR
Additional Information:	The copyright for this article belongs to NATL INST SCIENCE COMMUNICATION & INFORMATION RESOURCES-NISCAIR
Keywords:	(R)-Carvone; enantiospecific; Lewis acid; bicyclic lactones; lactonization
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	28 May 2019 12:28
Last Modified:	25 Sep 2022 06:07
URI:	https://eprints.iisc.ac.in/id/eprint/62614

Actions (login required)

View Item