Srikrishna, Adusumilli and Satyanarayana, Gedu (2019) Enantiospecific syntheses of oxacyclodecanes from carvone via mild Lewis acid mediated etherifcation. In: INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 58 (3, B). pp. 353-361.
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Official URL: http://nopr.niscpr.res.in/handle/123456789/45934?m...
Abstract
An efficient enantiospecific syntheses of oxatri-/tetra-cyclodecanes have been accomplished starting from (R)-carvone. A mild Lewis acid (BF3.OEt2) mediated intramolecular etherification is used as the key step. Structurally aesthetic tri- and tetracyclic ethers have been synthesized.
Item Type: | Journal Article |
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Publication: | INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY |
Publisher: | NATL INST SCIENCE COMMUNICATION & INFORMATION RESOURCES-NISCAIR |
Additional Information: | Copyright of this article belongs to NISCAIR-CSIR, India |
Keywords: | (R)-Carvone; terpenes; cyclic ethers; Lewis acid; etherification |
Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
Date Deposited: | 27 May 2019 05:50 |
Last Modified: | 25 Sep 2022 06:06 |
URI: | https://eprints.iisc.ac.in/id/eprint/62613 |
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