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Combustion Route to Fine Particle Perovskite Oxides

Manoharan, Sundar S and Patil, KC (1993) Combustion Route to Fine Particle Perovskite Oxides. In: Journal of Solid State Chemistry, 102 (1). pp. 267-276.

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Fine particle perovskite oxides such as $LnCrO_3$ (where Ln = La, Pr, Nd, Sm, Dy, Gd, and Y), $La_{1-x}Sr_xMnO_3$ (x = 0.0 to 0.5), $LaCoO_3$, and $LaNiO_3$ have been prepared by the combustion of corresponding metal nitrate-tetraformal trisazine (TFTA) mixtures at 350°C/500°C in a few minutes under ambient conditions. The oxides are of submicrometer size with specific surface area ranging from 3-20 $m^2/g$. The oxides have been characterized further by TEM and SEM studies. Sintering of $LaCrO_3$ at 1500°C for 2 hr resulted in 85% $(5.2 g/cm^3)$ of the theoretical density.

Item Type: Journal Article
Publication: Journal of Solid State Chemistry
Publisher: Elsevier
Additional Information: Copyright of this article belongs to Elsevier
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 28 Jun 2006
Last Modified: 19 Sep 2010 04:29
URI: http://eprints.iisc.ac.in/id/eprint/7718

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