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Enantiospecific synthesis of $tricyclo[^{4,8}]$decanes via acid catalysed rearrangement of isotwistanes

Srikrishna, A and Satyanarayana, G and Kumar, Ravi P (2006) Enantiospecific synthesis of $tricyclo[^{4,8}]$decanes via acid catalysed rearrangement of isotwistanes. In: Tetrahedron Letters, 47 (3). pp. 363-366.

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An acid catalyzed rearrangement was employed for the enantiospecific conversion of isotwistanol to tricyclo$[^{4,8}]$decanes, which provided support for the proposed biosynthesis of allopupukeananes from pupukeananes. The strategy has been further extended to the enantiospecific synthesis of a homobrexane.

Item Type: Journal Article
Publication: Tetrahedron Letters
Publisher: Elsevier BV
Additional Information: The copyright belongs to Elsevier BV.
Keywords: Molecular rearrangement;Isotwistanes;Pupukeananes;Allopupukeanane
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 17 Feb 2006
Last Modified: 19 Sep 2010 04:23
URI: http://eprints.iisc.ac.in/id/eprint/5388

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