Enantiospecific synthesis of $tricyclo[5.2.1.0^{4,8}]$decanes via acid catalysed rearrangement of isotwistanes

Srikrishna, A and Satyanarayana, G and Kumar, Ravi P (2006) Enantiospecific synthesis of $tricyclo[5.2.1.0^{4,8}]$decanes via acid catalysed rearrangement of isotwistanes. In: Tetrahedron Letters, 47 (3). pp. 363-366.

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Abstract

An acid catalyzed rearrangement was employed for the enantiospecific conversion of isotwistanol to tricyclo$[5.2.1.0^{4,8}]$decanes, which provided support for the proposed biosynthesis of allopupukeananes from pupukeananes. The strategy has been further extended to the enantiospecific synthesis of a homobrexane.

Item Type:	Journal Article
Publication:	Tetrahedron Letters
Publisher:	Elsevier BV
Additional Information:	The copyright belongs to Elsevier BV.
Keywords:	Molecular rearrangement;Isotwistanes;Pupukeananes;Allopupukeanane
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	17 Feb 2006
Last Modified:	19 Sep 2010 04:23
URI:	http://eprints.iisc.ac.in/id/eprint/5388

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