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Tris(tert-butyl 3-oxobutanoato-kappa O-2(1),O- )-aluminium(III) at 153 K

Dharmaprakash, MS and Thamotharan, Subbiah and Neelgund, GM and Shivashankar, SA (2006) Tris(tert-butyl 3-oxobutanoato-kappa O-2(1),O- )-aluminium(III) at 153 K. In: Acta Crystallographica Section E-Structure Reports Online, 62 (Part 3). M434-M436.

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Official URL: http://scripts.iucr.org/cgi-bin/paper?S16005368060...


In the title complex, [Al(C8H13O3)(3)], a potential metal-organic chemical vapour deposition (MOCVD) precursor, three bidentate ligand molecules are bound to the metal atom, forming an octahedral geometry. Two non-planar six-membered chelate rings adopt screw-boat conformations, while the third ring has a conformation that lies about halfway between an envelope and a screw-boat.

Item Type: Journal Article
Publication: Acta Crystallographica Section E-Structure Reports Online
Publisher: International Union of Crystallography
Additional Information: Copyright of this article belongs to International Union of Crystallography.
Keywords: Single-crystal X-ray study;T = 153 K;Mean (C–C) = 0.004 A° R factor = 0.058;wR factor = 0.157;Data-to-parameter ratio = 15.4.
Department/Centre: Division of Biological Sciences > Molecular Biophysics Unit
Division of Chemical Sciences > Materials Research Centre
Date Deposited: 16 Sep 2010 10:56
Last Modified: 19 Sep 2010 06:15
URI: http://eprints.iisc.ac.in/id/eprint/31781

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