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Decomposition of silane on solid P4O10

Suresh, BS and Padma, DK (1985) Decomposition of silane on solid P4O10. In: Polyhedron, 4 (12). 2067 -2068.

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Silane undergoes thermal decomposition on the surface of “phosphorus pentoxide” ( P4O10) into its elements around 200–400°C. The hydrogen formed partially reduces the P4O10 forming lower oxides of phosphorus and water. Elemental silicon is precipitated as reddish-brown solid, which is separated by dissolving out the phosphorus oxides. Silica and disiloxane are not formed in the reaction.

Item Type: Journal Article
Publication: Polyhedron
Publisher: Elsevier Science
Additional Information: Copyright of this article belongs to Elsevier Science.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 27 Jan 2010 06:05
Last Modified: 19 Sep 2010 05:44
URI: http://eprints.iisc.ac.in/id/eprint/23127

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