RS, Subrahmanya (1986) Kinetic currents in polarography. Part II. Spherical diffusion to the DME for pseudo-first order catalyzed processes and modification of Ilkovic equation. In: Journal of the Electrochemical Society of India, 35 (3). pp. 157-162.
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Introducing Ilkovic's limitation regarding the range of diffusion distance from the electrode surface into 3 dimensional spherical diffusion equation and combining it with the functional relationship, as also used by Kambara and Tachi, a differential equation for spherical diffusion to a growing electrode was formulated. Differential equations for spherical diffusion process to a growing Hg electrode for the cases involving chem. reactions occurring parallel to the electrode process were also formulated. The initial and the boundary conditions are given and the differential equation is solved by the Laplace transform method. A discussion of the modification of Ilkovic equation is also given
| Item Type: | Journal Article |
|---|---|
| Publication: | Journal of the Electrochemical Society of India |
| Publisher: | The Society,Bangalore. |
| Additional Information: | Copyright to this article belongs to The Society,Bangalore. Journal of the Electrochemical Society of India currently does not have a website |
| Keywords: | Kinetic currents;polarography;Spherical diffusion;DME;pseudo-first;catalyzed ;Ilkovic equation |
| Department/Centre: | Division of Chemical Sciences > Inorganic & Physical Chemistry |
| Date Deposited: | 04 Jul 2008 |
| Last Modified: | 27 Aug 2008 13:32 |
| URI: | http://eprints.iisc.ac.in/id/eprint/14786 |
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