Carbanion cyclisation of esters. Part 2:Enantiospecific construction of the tricyclic framework of the marine sesquiterpenes, spirodysins

Srikrishna, A and Kumar, Ravi P and Ramasastry, SSV (2004) Carbanion cyclisation of esters. Part 2:Enantiospecific construction of the tricyclic framework of the marine sesquiterpenes, spirodysins. In: Tetrahedron Letters, 45 (2). pp. 383-386.

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Abstract

Enantiospecific construction of the bicyclo[4.3.0]nonan-8-one 17 employing a lithium and liquid ammonia mediated carbanion cyclisation of the $\delta$-methyl-$\delta$,$\varepsilon$-unsaturated ester 13, and its elaboration to the tricyclic framework of the marine sesquiterpenes spirodysins are described.

Item Type:	Journal Article
Publication:	Tetrahedron Letters
Publisher:	Elsevier
Additional Information:	The copyright belongs to Elsevier.
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	02 Jun 2006
Last Modified:	19 Sep 2010 04:28
URI:	http://eprints.iisc.ac.in/id/eprint/7374

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