Sennappan, M and Murali Krishna, P and Managutti, PB and Mangasuli, SN and Malini, S (2021) Nucleic Acid Interaction and Photoluminescent Properties of Acylhydrazone and Its Mn(II), Co(II), Cu(II), Zn(II) and Cd(II) Complexes. In: Chemistry Africa, 4 (2). pp. 313-321.
Full text not available from this repository.Abstract
A (Z)-N'-benzylidene-2-hydroxy benzohydrazide (L) was prepared from salicylic acid hydrazide and benzaldehyde. The synthesized compound is structurally characterized by single crystal X-ray diffraction, elemental analysis, molar conductivity and spectroscopy (NMR, UV�Vis and FT-IR) techniques. The results of analytical methods indicate that the ligand is an acylhydrazone; possessing active groups easily take part in complexation with metal ions. Five metal complexes with formula MnL2 (1), CoL2 (2), CuL2 (3), ZnL2 (4) and CdL2 (5) were synthesized and characterized by various analytical (UV�Vis, FT-IR, Elemental (CHN) analysis and ESR) techniques. The interaction of ligand L and its complexes 1�5 with calf thymus DNA was carried out by electronic absorption spectroscopy. The results revealed that ligand L and its complexes 1�5 showed hypochromism. Photoluminescence properties of synthesized molecules were recorded and fluorescence intensity of molecules changes with excited wavelength. Graphic Abstract: Figure not available: see fulltext. © 2021, The Tunisian Chemical Society and Springer Nature Switzerland AG.
| Item Type: | Journal Article |
|---|---|
| Publication: | Chemistry Africa |
| Publisher: | Springer Science and Business Media Deutschland GmbH |
| Additional Information: | The copyright for this article belongs to Springer Science and Business Media Deutschland GmbH |
| Department/Centre: | Division of Chemical Sciences > Solid State & Structural Chemistry Unit |
| Date Deposited: | 20 Nov 2021 11:36 |
| Last Modified: | 20 Nov 2021 11:36 |
| URI: | http://eprints.iisc.ac.in/id/eprint/69903 |
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