Brillouin light scattering study of microscopic structure and dynamics in pyrrolidinium salt based ionic liquids

Das, S and Radhakrishnan, D and Bhadram, VS and Narayana, C and Bhattacharyya, AJ (2021) Brillouin light scattering study of microscopic structure and dynamics in pyrrolidinium salt based ionic liquids. In: Solid State Ionics, 363 .

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Abstract

Pyrrolidinium salts based ionic liquids are known to be good ionic conductors even in solid-state around room temperature, which is attributed to the highly disordered plastic crystalline phase. Moreover, these salts are characterized by multiple phase transitions which include plastic, structural glass, and glassy crystal phases with varying levels of molecular disorder. Temperature-dependent Brillouin light scattering is used to investigate the phase transitions in a series of alkylmethylpyrrolidinium Bis(trifluoromethanesulfonyl) imides (P1nTFSI, n = 1,2,4). Brillouin spectral features such as the number of acoustic modes, their shape, and linewidths provide the picture of different disordered phases resultant of dynamics at the microscopic scale. The longitudinal and transverse acoustic velocities in different phases are determined from the corresponding acoustic mode frequencies (Brillouin shift). Extremely low acoustic velocities in the solid phase of P11TFSI and P12TFSI are a consequence of a high degree of disorder and plasticity present in these systems. Anomalous temperature-dependent behavior of linewidths and asymmetric (Fano) line shape of acoustic modes observed in certain phases of P1nTFSI could be due to the strong coupling between the Brillouin central peak and the acoustic phonons. The present results establish that the Brillouin light scattering technique can be efficiently used to understand the complex phase behavior, microscopic structure, and dynamics of ionic liquids. © 2021 Elsevier B.V.

Item Type:	Journal Article
Publication:	Solid State Ionics
Publisher:	Elsevier B.V.
Additional Information:	The copyright for this article belongs to Elsevier B.V.
Keywords:	Acoustic wave velocity; Amines; Crystalline materials; Dynamics; Glass; Resonance; Salts, Brillouin light scattering; Fano resonances; Mechanical; Microscopic dynamics; Microscopic structures; N-alkyl-N-methyl pyrrolidinia bis(trifluoromethanesulfonyl) imide (P1nTFSI); Organic ionic plastic crystalline electrolyte; Property; Pyrrolidinium; Structure and dynamics, Ionic liquids
Department/Centre:	Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited:	29 Mar 2021 06:32
Last Modified:	29 Mar 2021 06:32
URI:	http://eprints.iisc.ac.in/id/eprint/68583

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