Prabhakaran, EN and Tumminakatti, S and Vats, K and Ghosh, S (2020) Spectral evidence for generic charge � acceptor interactions in carbamates and esters. In: RSC Advances, 10 (20). pp. 11871-11875.
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Official URL: https://doi.org/10.1039/d0ra00313a
Abstract
The correlations of the 1H NMR, 13C NMR and FT-IR spectral data from the R-O-CO groups in the alkyl carbamates and esters of homologous alcohols reveal R-group-dependent negative charge stabilization at the carbonyl oxygen and their donation to generic acceptors at Cα of even alkyl alcohols (R), which explains several of their apparently anomalous properties. This journal is © The Royal Society of Chemistry.
| Item Type: | Journal Article |
|---|---|
| Publication: | RSC Advances |
| Publisher: | Royal Society of Chemistry |
| Additional Information: | Copyright for this article belongs to Royal Society of Chemistry |
| Keywords: | 13C NMR; Alkyl alcohols; Alkyl carbamate; Carbonyl oxygen; Co-group; IR spectral data; Negative charge, Esters |
| Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
| Date Deposited: | 09 Apr 2021 10:08 |
| Last Modified: | 09 Apr 2021 10:08 |
| URI: | http://eprints.iisc.ac.in/id/eprint/65168 |
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