Enantioselective Total Synthesis of Valeriananoids A-C

Srikrishna, A and Satyanarayana, G (2004) Enantioselective Total Synthesis of Valeriananoids A-C. In: Organic Letters, 6 (14). pp. 2337-2339.

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Abstract

The first enantioselective total synthesis of valeriananoids A-C (-)-1-3 is reported starting from the readily available monoterpene (R)- carvone, employing a tandem intermolecular Michael addition-intramolecular Michael addition-alkylation sequence and an electron-transfermediated 6-endo-trig cyclization as key steps.

Item Type:	Journal Article
Publication:	Organic Letters
Publisher:	American Chemical Society
Additional Information:	The copyright belongs to American Chemical Society.
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	02 May 2006
Last Modified:	19 Sep 2010 04:26
URI:	http://eprints.iisc.ac.in/id/eprint/6501

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