Sarkar, Sumana and Datta, Ayan and Mondal, Amrita and Chopra, Deepak and Ribas, Joan and Rajak, Kajal Krishna and Sairam, SM and Pati, Swapan K (2006) Competing Magnetic Interactions in a Dinuclear Ni(II) Complex: Antiferromagnetic O-H...O Moiety and Ferromagnetic $N_{3}^{-}$ Ligand. In: Journal of Physical Chemistry B, 110 (1). pp. 12-15.
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Abstract
Synthesis, structural characteristics, magnetic studies and DFT calculations in Ni(II) dinuclear complexes containing two bridging $N_{3}^{-}$ and an O-H...O linkage reveal the existence of ferromagnetic interactions between Ni(II) centers via $N_{3}^{-}$ ligands and antiferromagntic interactions through the H-bonded moiety. The overall magnetic behavior of the system depends on the delicate balance between these two competing interactions.
Item Type: | Journal Article |
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Publication: | Journal of Physical Chemistry B |
Publisher: | American Chemical Society |
Additional Information: | Copyright for this article belongs to American Chemical Society. |
Department/Centre: | Division of Chemical Sciences > Solid State & Structural Chemistry Unit |
Date Deposited: | 28 Feb 2006 |
Last Modified: | 19 Sep 2010 04:24 |
URI: | http://eprints.iisc.ac.in/id/eprint/5741 |
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