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Reversible phase transition and relaxor behavior in Te2V2O9 single crystals grown by Czochralski technique

Shet, Tukaram and Varma, KBR (2016) Reversible phase transition and relaxor behavior in Te2V2O9 single crystals grown by Czochralski technique. In: JOURNAL OF CRYSTAL GROWTH, 449 . pp. 57-61.

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Official URL: http://dx.doi.org/10.1016/j.jcrysgro.2016.05.043

Abstract

Te2V2O9 single crystals were grown along the polar c-axis via the Czochralski crystal growth technique. Dielectric studies carried out along the polar axis in a wide temperature range at different frequencies confirmed the relaxor nature of the Te2V2O9 single crystals. Temperature dependent polarized light optical microscopy along alpha-axis established a reversible phase transition around 614 K. Relaxor nature of Te2V2O9 was attributed to the compositional heterogeneity at micro/nano scale within the grown crystal as vanadium was observed to be present in different oxidation states by X-ray photoelectron spectroscopic studies. (C) 2016 Elsevier B.V. All rights reserved.

Item Type: Journal Article
Publication: JOURNAL OF CRYSTAL GROWTH
Additional Information: Copy right for this article belongs to the ELSEVIER SCIENCE BV, PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS
Department/Centre: Division of Chemical Sciences > Materials Research Centre
Date Deposited: 22 Oct 2016 05:50
Last Modified: 22 Oct 2016 05:50
URI: http://eprints.iisc.ac.in/id/eprint/54644

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