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Enantiospecific first total synthesis of $(+)-2\beta-hydroxysolanascone$, the aglycone of the phytoalexin isolated from flue-cured tobacco leaves

Srikrishna, A and Ramasastry, SSV (2006) Enantiospecific first total synthesis of $(+)-2\beta-hydroxysolanascone$, the aglycone of the phytoalexin isolated from flue-cured tobacco leaves. In: Tetrahedron Letters, 47 (3). pp. 335-339.

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Abstract

The first total synthesis of $(+)-2\beta-hydroxysolanascone$, the aglycon of the phytoalexin $2\beta-hydroxysolanascone-\beta-glucopyranoside$ isolated from flue-cured tobacco leaves (N. tabacum L., OCL), and its 2,10-diepi- and $2\propto-epimers$ has been accomplished, starting from the readily available monoterpene (R)-carvone.

Item Type: Journal Article
Publication: Tetrahedron Letters
Publisher: Elsevier BV
Additional Information: The Copyright belongs to Elsevier BV.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 17 Feb 2006
Last Modified: 19 Sep 2010 04:23
URI: http://eprints.iisc.ac.in/id/eprint/5389

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