An Efficient Tertiary Azidation of 1,3-Dicarbonyl Compounds in Water Catalyzed by Tetrabutylammonium Iodide

Dhineshkumar, Jayaraman and Prabhu, Kandikere Ramaiah (2016) An Efficient Tertiary Azidation of 1,3-Dicarbonyl Compounds in Water Catalyzed by Tetrabutylammonium Iodide. In: EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (3). pp. 447-452.

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Abstract

An efficient azidation of 1,3-dicarbonyl compounds led to tertiary azides in the presence of tetrabutylammonium iodide (TBAI). TBAI is used as a pre-catalyst along with aq. tert-butyl hydroperoxide (TBHP) as an oxidant in aqueous medium. This operationally simple, practical, mild and green method provides an opportunity to synthesize a variety of azidated -keto esters, amides, and ketones in good yields.

Item Type:	Journal Article
Publication:	EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Publisher:	WILEY-V C H VERLAG GMBH
Additional Information:	Copy right for this article belongs to the WILEY-V C H VERLAG GMBH, POSTFACH 101161, 69451 WEINHEIM, GERMANY
Keywords:	Azides; Iodine; Keto esters; 1,3-Dicarbonyl compounds; Synthetic methods
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	18 Feb 2016 06:02
Last Modified:	18 Feb 2016 06:02
URI:	http://eprints.iisc.ac.in/id/eprint/53280

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