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Light Induced Metastable State of Silver Nitroprusside Probed by Raman Spectroscopy

Ghalsasi, Pallavi and Ghalsasi, Prasanna and Thomas, A and Muthu, DVS and Sood, AK (2015) Light Induced Metastable State of Silver Nitroprusside Probed by Raman Spectroscopy. In: 59th DAE Solid State Physics Symposium, DEC 16-20, 2014, VIT Univ, Vellore, INDIA.

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Official URL: http://dx.doi.org/10.1063/1.4917606

Abstract

Low temperature Raman spectroscopic measurements on silver nitroprusside (AgNP), Ag-2Fe(CN)(5)NO] powders display reversible features of a partially converted metastable state. The results are compared with similarly observed metastable state in case of sodium nitroprusside (NaNP) and the differences have been discussed in terms of possible resistance to metastable state formation offered by silver atoms on the basis of hard soft acid base (HSAB) theory.

Item Type: Conference Proceedings
Series.: AIP Conference Proceedings
Publisher: AMER INST PHYSICS
Additional Information: Copy right for this article belongs to the AMER INST PHYSICS, 2 HUNTINGTON QUADRANGLE, STE 1NO1, MELVILLE, NY 11747-4501 USA
Keywords: Nitroprusside; Metastable state; Raman spectroscopy
Department/Centre: Division of Physical & Mathematical Sciences > Physics
Date Deposited: 14 Jan 2016 04:28
Last Modified: 14 Jan 2016 04:28
URI: http://eprints.iisc.ac.in/id/eprint/53109

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