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Conductometric Sensing of H-2 by Chromium Niobate

Murthy, Sree Rama A and Gnanasekar, KI and Jayaraman, V and Umarji, AM and Gnanasekaran, T (2015) Conductometric Sensing of H-2 by Chromium Niobate. In: IEEE SENSORS JOURNAL, 15 (12). pp. 7054-7060.

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Official URL: http://dx.doi.org/10.1109/JSEN.2015.2470102

Abstract

Investigations on chromium niobate (CrNbO4) have shown that the material responds to a wide hydrogen concentration range of 0.01%-0.40% at 613 K. The conductivity of CrNbO4 is independent of oxygen partial pressure and offers to be a promising candidate for monitoring H-2 in radioactive spent fuel storage facilities. Reduction of metal ions to lower valence states during hydrogen sensing was evidenced by X-ray photoelectron spectroscopic studies.

Item Type: Journal Article
Publication: IEEE SENSORS JOURNAL
Publisher: IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC
Additional Information: Copy right for this article belongs to the IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC, 445 HOES LANE, PISCATAWAY, NJ 08855-4141 USA
Keywords: Chromium niobate; hydrogen sensing; X-ray photoelectron spectroscopy
Department/Centre: Division of Chemical Sciences > Materials Research Centre
Date Deposited: 14 Jan 2016 06:17
Last Modified: 14 Jan 2016 06:17
URI: http://eprints.iisc.ac.in/id/eprint/53089

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