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Growth and characterization of L-histidinium 2-nitrobenzoate single crystals: A new NLO material

Moovendaran, K and Dhas, Martin Britto SA and Natarajan, S (2013) Growth and characterization of L-histidinium 2-nitrobenzoate single crystals: A new NLO material. In: OPTIK, 124 (17). pp. 3117-3119.

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Official URL: http://dx.doi.org/10.1016/j.ijleo.2012.09.042

Abstract

Crystals of a new nonlinear optical (NLO) material, viz., L-histidinium 2-nitrobenzoate (LHNB) (1) were grown by slow evaporation of an aqueous solution containing equimolar concentrations of L-histidine and 2-nitrobenzoic acid. The structure of the title compound which crystallizes in the non-centrosymmetric monoclinic space group P2(1) was elucidated using single crystal X-ray intensity data. The UV-Vis-NIR spectrum of 1 reveals its transparent nature while the vibrational spectra confirm the presence of the functional groups in 1. The thermal stability and second harmonic generation (SHG) conversion efficiency of 1 were also investigated. (C) 2012 Elsevier GmbH. All rights reserved.

Item Type: Journal Article
Publication: OPTIK
Publisher: ELSEVIER GMBH, URBAN & FISCHER VERLAG
Additional Information: Copyright for this article belongs to Elsevier Science
Keywords: Crystal growth; FTIR; Thermal analysis; Non-linear optical material
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 08 Oct 2013 11:16
Last Modified: 08 Oct 2013 11:16
URI: http://eprints.iisc.ac.in/id/eprint/47453

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