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Explorations en route to synthesis of tashironins: singlet oxygen cycloaddition to 1,3-cyclopentadienes embedded within allo-cedrane framework

Mehta, Goverdhan and Maity, Pulakesh (2011) Explorations en route to synthesis of tashironins: singlet oxygen cycloaddition to 1,3-cyclopentadienes embedded within allo-cedrane framework. In: Tetrahedron Letters, 52 (40). pp. 5161-5165.

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Official URL: http://dx.doi.org/10.1016/j.tetlet.2011.07.120

Abstract

In an approach directed toward a tashironin based complex natural product, efficacy of the singlet oxygen mediated [4+2]-cycloaddition to a tetracyclic cyclopentadiene has been evaluated to install the key cis-1,4-dihydroxy functionality. (C) 2011 Elsevier Ltd. All rights reserved.

Item Type: Journal Article
Publication: Tetrahedron Letters
Publisher: Elsevier Science
Additional Information: Copyright of this article belongs to Elsevier Science.
Keywords: Natural product synthesis;Polycyclic compounds; Cycloaddition;Singlet oxygen;Rearrangement
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 04 Nov 2011 09:32
Last Modified: 04 Nov 2011 09:32
URI: http://eprints.iisc.ac.in/id/eprint/41824

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