Linkage isomerism in 4-(2-aminoethyl)morpholine (L) complexes of nickel(II) nitrite: X-ray single crystal structure of trans-$[NiL_{2}(NO_{2})_{2}]$

Chattopadhyay, Tanmay and Ghosh, Manami and Majee, Adinath and Nethaji, Munirathinam and Das, Debasis (2005) Linkage isomerism in 4-(2-aminoethyl)morpholine (L) complexes of nickel(II) nitrite: X-ray single crystal structure of trans-$[NiL_{2}(NO_{2})_{2}]$. In: Polyhedron, 24 (13). pp. 1677-1681.

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Abstract

The linkage isomers trans-bis[4-(2-aminoethyl)morpholine]dinitronickel(II) (brown, 1a) andtrans-bis[4-(2-aminoethyl)morpholine]dinitritonickel (II) (blue-violet,1b) have been synthesized from solution. Complex la is the major and thermodynamically controlled product, where as, complex 1b is minor and kinetically controlled product. The X-ray single crystal structure analysis of complex la has been performed.

Item Type:	Journal Article
Publication:	Polyhedron
Publisher:	Pergamon-Elsevier Science Ltd
Additional Information:	Copyright for this article belongs to Elsevier.
Keywords:	Linkage isomerism;4-(2-Aminoethyl)morpholine;Nickel (II) nitrite
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	24 Oct 2005
Last Modified:	19 Sep 2010 04:20
URI:	http://eprints.iisc.ac.in/id/eprint/3890

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