Prasad, Kavirayani R and Gutala, Phaneendra (2011) Enantioselective total synthesis of macrosphelides A and E. In: Tetrahedron, 67 (25). pp. 4514-4520.
PDF
Enantioselective.pdf - Published Version Restricted to Registered users only Download (435kB) | Request a copy |
Official URL: http://dx.doi.org/10.1016/j.tet.2011.04.099
Abstract
Enantioselective synthesis of 16-membered trilactone macrolides, macrosphelide A and E from (S)-lactic acid is described. Key features of the synthesis include the utility of a hitherto unexplored beta-ketophosphonate derived from lactic acid and Yamaguchi lactonization leading to the title compounds. (C) 2011 Elsevier Ltd. All rights reserved.
Item Type: | Journal Article |
---|---|
Publication: | Tetrahedron |
Publisher: | Elsevier Science |
Additional Information: | Copyright of this article belongs to Elsevier Science. |
Keywords: | Total synthesis;Macrolactone;Lactic acid;Macrosphelides |
Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
Date Deposited: | 05 Jul 2011 10:11 |
Last Modified: | 05 Jul 2011 10:11 |
URI: | http://eprints.iisc.ac.in/id/eprint/38868 |
Actions (login required)
View Item |