Shafi, KVPM and Sathyanarayana, DN (1998) Thermal analysis studies on hydroxobridged homo and hetero trinuclear cobalt(III) complexes. In: Journal of Thermal Analysis, 51 (2). pp. 567-574.
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The synthesis and thermal analysis studies of several hydroxobridged homo and hetero trinuclear cobalt(III) complexes are reported. The complexes are of the type [M(H2O)(x) {(OH)(2)Co(en)(2)}(2)](SO4)(2). nH(2)O and [M(H2O)(x){(OH)(2)Co(NH3)(4)}(2)] (SO4)(2). nH(2)O where en denotes ethylenediamine and M =Co(II), Ni(II), Cu(II) and Zn(II) with x=0 for Cu(II), and 2 for other metal ions, and n =3, 4 or 5. The TG and DTA studies of these compounds show that one or more intermediate compounds are formed in each case before the metal oxides are produced.
| Item Type: | Journal Article |
|---|---|
| Publication: | Journal of Thermal Analysis |
| Publisher: | Kluwer Academic Publ |
| Additional Information: | Copyright of this article belongs to Kluwer Academic Publ. |
| Keywords: | Complexes;hydroxobridged;TG-DTA;trinuclear complexes. |
| Department/Centre: | Division of Chemical Sciences > Inorganic & Physical Chemistry |
| Date Deposited: | 12 Jul 2011 07:45 |
| Last Modified: | 12 Jul 2011 07:45 |
| URI: | http://eprints.iisc.ac.in/id/eprint/38790 |
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