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Oxidation of substituted benzylic hydrocarbons and naphthalenes by peroxydisulphate in the presence of metal ions

Perumal, PT and Bhatt, MV (1995) Oxidation of substituted benzylic hydrocarbons and naphthalenes by peroxydisulphate in the presence of metal ions. In: Proceedings of the Indian Academy of Sciences - Chemical Sciences, 107 (5). pp. 567-572.

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Abstract

Oxidations of various substituted benzylic hydrocarbons with peroxydisulphate in the presence of metal ion catalysts like iron, nickel, copper, cobalt, silver and cerium were examined. Among the metal ions copper (II) catalysed reaction gives products in excellent yield, whereas oxidation of naphthalene and substituted naphthalenes gives low to moderate yield of the products with peroxydisulphate- copper (II).

Item Type: Journal Article
Publication: Proceedings of the Indian Academy of Sciences - Chemical Sciences
Publisher: Indian Academy of Sciences
Additional Information: Copyright of this article belongs to Indian Academy of Sciences.
Keywords: Metal ion catalysed oxidation;benzylic hydrocarbons; substituted naphthalenes and potassium peroxydisulphate.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 24 May 2011 04:50
Last Modified: 24 May 2011 04:50
URI: http://eprints.iisc.ac.in/id/eprint/37840

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