KN, Radhamani and Anil, Eliasa J and DK, Padma (1992) High Yield Room Temperature Synthesis And Spectral Studies Of Tri(Amino)Silanes: (R2n)3SIH. In: Phosphorus, Sulfur, and Silicon and the Related Elements, 66 (1-4). pp. 297-300.
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Tri(amino)silanes were prepared by the condensation of trichlorosilane with secondary amines in 1:6 molar ratio. Reactions of trichlorosilane with pyrrolidine, piperidine, hexamethyleneimine, morpholine, N-methylpiperazine and diethylamine afford the tri(amino)silanes in nearly quantitative yields. Their physical and spectroscopic properties are discussed. All these compounds are highly sensitive to moisture and hydrolyse to silica and the respective amine with the evolution of hydrogen. The compounds have been characterised by IR, 1H NMR, [1H]29Si NMR spectroscopic methods and CHN elemental analysis.
| Item Type: | Editorials/Short Communications |
|---|---|
| Publication: | Phosphorus, Sulfur, and Silicon and the Related Elements |
| Publisher: | Gordon Breach Sci Publ Ltd |
| Additional Information: | Copyright of this article belongs to Gordon Breach Sci Publ Ltd. |
| Keywords: | Pyrrolidine;piperidine;hexamethyleneimine;morpholine; N-methylpiperazine;diethylamine. |
| Department/Centre: | Division of Chemical Sciences > Inorganic & Physical Chemistry |
| Date Deposited: | 01 Apr 2011 09:14 |
| Last Modified: | 01 Apr 2011 09:14 |
| URI: | http://eprints.iisc.ac.in/id/eprint/36318 |
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