Synthesis of Functionalized Dihydrothiophenes from Doubly Activated Cyclopropanes Using Tetrathiomolybdate as the Sulfur Transfer Reagent

Gopinath, Purushothaman and Chandrasekaran, Srinivasan (2011) Synthesis of Functionalized Dihydrothiophenes from Doubly Activated Cyclopropanes Using Tetrathiomolybdate as the Sulfur Transfer Reagent. In: Journal of Organic Chemistry, 76 (2). pp. 700-703.

PDF Synthesis.pdf - Published Version Restricted to Registered users only Download (1MB) | Request a copy

Abstract

A number of doubly activated cyclopropanes were synthesized starting from various substituted bromosulfonium bromides in good yield. Regioselective ring-opening of cyclopropanes with tetrathiomolybdate as the sulfur transfer reagent gave dihydrothiophenes in excellent yield.

Item Type:	Journal Article
Publication:	Journal of Organic Chemistry
Publisher:	American Chemical Society
Additional Information:	Copyright of this article belongs to American Chemical Society.
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	04 Mar 2011 06:41
Last Modified:	04 Mar 2011 06:41
URI:	http://eprints.iisc.ac.in/id/eprint/35809

Actions (login required)

View Item