Bhat, GA (1978) Electrochemical reduction of Cu(II)-CyDTA complex at dropping mercury electrode. An impedance approach. In: Proceedings of the Indian Academy of Sciences - Section A, 87 (12). 447-454 .
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Abstract
The electrochemical reduction of Cu(II)-CyDTA (CyDTA — trans 1,2-cyclohexanediamine N, N, N′, N′ tetraacetic acid) by impedance method reveals the unusual behaviour of complex plane polarograms owing to potential dependence of double layer capacitance. The impedance plane plots by frequency variation method indicates the quasi-reversible nature of the system. From these plots the chargetransfer resistance at various potentials was evaluated. The standard rate constant was evaluated which complements the prediction of impedance plots for the quasireversible behaviour of the system.
Item Type: | Journal Article |
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Publication: | Proceedings of the Indian Academy of Sciences - Section A |
Publisher: | Indian Academy of Sciences |
Additional Information: | Copyright of this article belongs to Indian Academy of Sciences. |
Keywords: | Electrochemical reduction - Cu-CyDTA system - impedance method - complex plane polarography . |
Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
Date Deposited: | 26 Oct 2010 08:36 |
Last Modified: | 26 Oct 2010 08:36 |
URI: | http://eprints.iisc.ac.in/id/eprint/33244 |
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