Kanagapushpam, D and Venkatesan, K and Cameron, TS (1988) Studies in nonlinear optical materials: structure of di-2-menthyl 2-(N,N'-dimethyl-2-imidazolidinylidene)malonate monohydrate. In: Acta Crystallographica Section C, 44 . pp. 337-340.
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Abstract
C28H48N2Oa.H2 O, Mr=494.7, orthorhombic,P2~2~2~, a = 7.634 (2), b = 11.370 (2), c=34. 167 (4) A, V = 2966 (2) A 3, Z = 4, D m = 1.095,D x -- 1. 108 g cm -3, Mo Kct, 2 -- 0.7107 ,/k, ~ =0.43 cm -~, F(000) = 1088.0, T= 293 K, R = 0.061 for 1578 significant reflections. The second-harmonicgeneration (SHG) efficiency of this compound is negligible (1/100th of the urea standard). The observed low second-order nonlinear response has been attributed to the unfavourable packing of the molecules in the crystal lattice.
Item Type: | Journal Article |
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Publication: | Acta Crystallographica Section C |
Publisher: | International Union of Crystallography |
Additional Information: | Copyright of this article belongs to International Union of Crystallography. |
Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
Date Deposited: | 05 Oct 2010 09:17 |
Last Modified: | 05 Oct 2010 09:17 |
URI: | http://eprints.iisc.ac.in/id/eprint/32972 |
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