Chandrasekhar, Sosale and Sridhar, Malayalam (2000) A bifunctional approach towards the mild oxidation of organic halides: 2-dimethylamino-N,N-dimethylaniline N-oxide. In: Tetrahedron Letters, 41 (28). 5423-5425 .
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Official URL: http://dx.doi.org/10.1016/S0040-4039(00)00874-1
Abstract
The titled reagent incorporates an oxygen-centred nucleophile and a basic moiety�in a suitably mutual orientation�in the same molecule. It oxidises various primary benzylic bromides to the corresponding aromatic aldehydes under relatively mild conditions (MeCN/rt�50°C/6�24 h) in high yields (83�97%), and is thus a useful alternative to the Kornblum procedure.
| Item Type: | Journal Article |
|---|---|
| Publication: | Tetrahedron Letters |
| Publisher: | Elsevier Science |
| Additional Information: | Copyright of this article belongs to Elsevier Science. |
| Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
| Date Deposited: | 30 Sep 2010 10:05 |
| Last Modified: | 30 Sep 2010 10:05 |
| URI: | http://eprints.iisc.ac.in/id/eprint/32538 |
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