Quinone studies. Part III. Metal ion-catalysed oxidation of halophenols and halonaphthols by peroxidisulphate

Perumal, Thirumalai P and Bhatt, Vivekananda M (1989) Quinone studies. Part III. Metal ion-catalysed oxidation of halophenols and halonaphthols by peroxidisulphate. In: Proceedings of the Indian Academy of Sciences - Chemical Sciences, 101 (1). pp. 25-32.

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Abstract

Oxidation of representative halophenols and halonaphthols by peroxidisulphate has been examined. The influence of metallic ions, viz. Cu2+, Fe3+, Ag+, on the above reaction has been studied. Cu2+ ion-catalyzed oxidation gives halo-1, 4-quinones in excellent yield. Potassium bis(biureto)cuprate(III) complex also oxidises halophenols to halo-1, 4-quinones.

Item Type:	Journal Article
Publication:	Proceedings of the Indian Academy of Sciences - Chemical Sciences
Publisher:	Indian Academy of Sciences
Additional Information:	Copyright of this article belongs to Indian Academy of Sciences.
Keywords:	Metal ion-catalysed oxidation -halophenols -halonaphthols - peroxidisulphate -halo-1,4-quinones
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	25 Aug 2010 05:06
Last Modified:	19 Sep 2010 06:14
URI:	http://eprints.iisc.ac.in/id/eprint/31401

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