Anil, Kumar R and Chandrasekhar, Sosale (2000) Improved procedures for the Beckmann rearrangement: the reaction of ketoxime carbonates with boron trifluoride etherate. In: Tetrahedron Letters, 41 (28). pp. 5427-5429.
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Official URL: http://dx.doi.org/10.1016/S0040-4039(00)00875-3
Abstract
A variety of ketoxime ethyl carbonates-easily prepared from the oximes and ethyl chloroformate-undergo the Beckmann rearrangement upon treatment with 1 equivalent of boron trifluoride etherate, in dichloromethane solution at room temperature in excellent yields (generally 75-99%). (C) 2000 Elsevier Science Ltd. All rights reserved.
Item Type: | Journal Article |
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Publication: | Tetrahedron Letters |
Publisher: | Elsevier Science |
Additional Information: | Copyright of this article belongs to Elsevier Science. |
Keywords: | Beckmann rearrangement;boron trifluoride;ethylchloroformate; oxime carbonates |
Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
Date Deposited: | 09 Aug 2010 05:53 |
Last Modified: | 21 Feb 2019 09:06 |
URI: | http://eprints.iisc.ac.in/id/eprint/31167 |
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