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Studies in sesquiterpenes-XVI. Zerumbone, a monocyclic sesquiterpene ketone

Dev, Sukh (1960) Studies in sesquiterpenes-XVI. Zerumbone, a monocyclic sesquiterpene ketone. In: Tetrahedron, 8 (3-4). pp. 171-180.

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Official URL: http://dx.doi.org/10.1016/0040-4020(60)80027-0

Abstract

The structure, previously assigned to zerumbone, has been found to be untenable. The ketone has been shown to be monocyclic containing three ethylenic linkages, and has been further correlated with humulene. Results from ozonolysis, and base-catalysed cleavage allowed the compound to be formulated as 2,6,9,9-tetramethyl-2,6,10-cyclo-undecatrien-1-one.

Item Type: Journal Article
Publication: Tetrahedron
Publisher: Elsevier Science
Additional Information: Copyright of this article belongs to Elsevier Science.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 23 Jun 2010 05:44
Last Modified: 19 Sep 2010 06:09
URI: http://eprints.iisc.ac.in/id/eprint/28517

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