Cerimetry in non-aqueous media - Oxidation of oxalic acid through the intermediate formation of ceric oxalate

Rao, Prabhakar G and Vasudeva Murthy, AR (1963) Cerimetry in non-aqueous media - Oxidation of oxalic acid through the intermediate formation of ceric oxalate. In: Fresenius' Zeitschrift für Analytische Chemie, 195 (6). pp. 406-411.

PDF Cerm.pdf - Published Version Restricted to Registered users only Download (390kB) | Request a copy

Abstract

It was found that ceric oxalate is an intermediate product in the oxidation of oxalic acid by ammonium hexanitrato cerate in solvents such as acetonitrile, and a mixture of acetonitrile and glacial acetic acid. Conditions for the formation of ceric oxalate and its decomposition into carbon dioxide and cerous oxalate have been studied. An analytical method for the estimation of oxalic acid in non-aqueous media has been evolved based on this reaction.

Item Type:	Journal Article
Publication:	Fresenius' Zeitschrift für Analytische Chemie
Publisher:	Springer
Additional Information:	Copyright of this article belongs to Springer.
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	02 Jun 2010 09:27
Last Modified:	19 Sep 2010 06:08
URI:	http://eprints.iisc.ac.in/id/eprint/28181

Actions (login required)

View Item