Dimethyl sulphoxide and dimethyl formamide complexes of Mn(III) perchlorate

Prabhakaran, CP and Patel, CC (1968) Dimethyl sulphoxide and dimethyl formamide complexes of Mn(III) perchlorate. In: Journal of Inorganic and Nuclear Chemistry, 30 (3). pp. 867-869.

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Abstract

Dimethyl sulphoxide (DMSO) and dimethyl formamide (DMF) complexes of Mn(III) perchlorate have been prepared and their conductivity, magnetic susceptibility and i.r. and electronic spectra studied. The complexes behave as uni-trivalent electrolytes in acetonitrile. Their magnetic moments of 5·1 B.M. show them to be of high spin type. Infra-red spectra show that oxygen is the donor atom in both complexes. The spin allowed electronic transition for d4 system, around 20,000 cm−1, ascribable to the 5Eg → 5T2g transition, suggests an octahedral configuration for these complexes

Item Type:	Journal Article
Publication:	Journal of Inorganic and Nuclear Chemistry
Publisher:	Elsevier Science
Additional Information:	Copy right of this article belongs to Elsevier Science.
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	14 May 2010 05:19
Last Modified:	19 Sep 2010 06:06
URI:	http://eprints.iisc.ac.in/id/eprint/27734

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