Srikrishna, A and Ramachary, DB (2005) Approaches to sesquiterpenes containing three contiguous quaternary carbon atoms. Synthesis of 3-methoxythapsene. In: Indian Journal of Chemistry - Section B: Organic and Medicinal Chemistry, 44 (4). pp. 751-761.
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Official URL: http://www3.interscience.wiley.com/journal/1105743...
Abstract
Synthetic approach to 3-alkoxythapsane, comprising of the carbon framework of a small group of sesquiterpenes containing three contiguous quaternary carbon atoms has been described. A combination of alkylation, orthoester Claisen rearrangement and intramolecular diazoketone cyclopropanation has been employed for the creation of the three requisite contiguous quaternary carbon atoms.
| Item Type: | Journal Article |
|---|---|
| Publication: | Indian Journal of Chemistry - Section B: Organic and Medicinal Chemistry |
| Publisher: | National Institute of Science Communication and Information Resources |
| Additional Information: | Copyright of this article belongs to National Institute of Science Communication and Information Resources. |
| Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
| Date Deposited: | 09 Jun 2010 04:47 |
| Last Modified: | 09 Jun 2010 04:47 |
| URI: | http://eprints.iisc.ac.in/id/eprint/27218 |
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