Mehta, Goverdhan and Pan, Subhas Chandra (2004) Total Synthesis of the Novel, Biologically Active Epoxyquinone Dimer (\pm)-Torreyanic Acid: A Biomimetic Approach. In: Organic Letters, 6 (22). pp. 3985-3988.
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Official URL: http://pubs.acs.org/doi/abs/10.1021/ol0483551
Abstract
A total synthesis of the complex, biologically active, dimeric natural product (\pm)-torreyanic acid, which is composed of seven rings and laced with dense, variegated oxy-functionalization, has been accomplished from readily available allyl-substituted p-benzoquinone 8. Our synthetic stratagem involves crafting an epoxyquinone monomer for use in a biomimetic cascade process involving tandem a 6\pi electrocyclization and a Diels-Alder dimerization.
Item Type: | Journal Article |
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Publication: | Organic Letters |
Publisher: | American Chemical Society |
Additional Information: | Copyright for this article belongs to American Chemical Society. |
Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
Date Deposited: | 22 Nov 2007 |
Last Modified: | 19 Jan 2012 05:03 |
URI: | http://eprints.iisc.ac.in/id/eprint/2650 |
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