Ganesh, Venkataraman and Chandrasekaran, Srinivasan (2009) One-Pot Synthesis of beta-Amino/beta-Hydroxy Selenides and Sulfides from Aziridines and Epoxides. In: Synthesis-Stuttgart (19). pp. 3267-3278.
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Abstract
Diaryl disulfides and diselenides undergo facile cleavage on treatment with rongalite (sodium hydroxymethanesulfinate) to generate the corresponding thiolate and selenolate species in Situ, which effect the ring opening of aziridines and epoxides in a regioselective manner. A simple, mild, cost-effective protocol has been developed to prepare beta-amino and beta-hydroxy sulfides and selenides in a one-pot operation.
Item Type: | Journal Article |
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Publication: | Synthesis-Stuttgart |
Publisher: | Thieme Medical Publishers, Inc. and Georg Thieme Verlag |
Additional Information: | Copyright for this article belongs to Thieme Medical Publishers, Inc. and Georg Thieme Verlag. |
Keywords: | beta-amino selenide; beta-amino sulfide; beta-hydroxy selenide; beta-hydroxy sulfide; rongalite; aziridine; epoxide |
Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
Date Deposited: | 09 Dec 2009 09:57 |
Last Modified: | 19 Sep 2010 05:52 |
URI: | http://eprints.iisc.ac.in/id/eprint/24905 |
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