Aspects of tautomerism. 8. Solvolysis of some pseudo and normal acid chlorides

Bhatt, Vivekananda M and Ashry, Shaker HEl and Balakrishnan, M (1979) Aspects of tautomerism. 8. Solvolysis of some pseudo and normal acid chlorides. In: Journal of Chemical Sciences, 88 (6). pp. 421-437.

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Abstract

Pseudo acid chlorides derived from levulinic acid ando-benzoyl-benzoic acid, solvolyse in aqueous acetone, aqueous dioxane and aqueous dimethylformamide by aS Nl process. Their reaction pattern is distinct from that of typical normal acid chlorides, viz.,p-benzoylbenzoyl chloride and fluorene-9-one-1-carboxylic acid chloride, which solvolyse by aS N2 pathway. No evidence for tautomerism could be obtained either between the normal and pseudo forms of the acid chlorides or the derived ion pairs.

Item Type:	Journal Article
Publication:	Journal of Chemical Sciences
Publisher:	Springer India, in co-publication with Indian Academy of Sciences
Additional Information:	Copyright of this article belongs to Springer.
Keywords:	Tautomerism;pseudo acid chloride;solvolysis.
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	27 Oct 2009 13:24
Last Modified:	21 Feb 2019 10:43
URI:	http://eprints.iisc.ac.in/id/eprint/24767

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