Sastry, VSS and Ramakrishna, J (1979) Zeeman effect of NQR in 4,6-dichloropyrimidine and 6-chloro 2,4-dimethoxypyrimidine. In: Pramana, 13 (3). pp. 219-222.
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Abstract
Zeeman (35Cl) NQR studies in polycrystalline samples of 4,6-dichloropyrimidine and 6 chloro 2,4 dimethoxypyrimidine show that the asymmetry at the four chemically inequivalent chlorine sites in the former is about 10%, while in the latter (one line) the asymmetry is almost zero. Using a valence-bond picture, C-Cl bonds in 4,6-dichloropyrimidine have been characterised, and the results are also compared with those in a corresponding benzene compound using a simple molecular orbital calculation. The axial symmetry of C-Cl bond in the second compound has been attributed to mesomeric effects.
Item Type: | Journal Article |
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Publication: | Pramana |
Publisher: | Indian Academy of Sciences |
Additional Information: | Copy right of this article belongs to Indian Academy of Sciences. |
Department/Centre: | Division of Physical & Mathematical Sciences > Physics |
Date Deposited: | 05 Jan 2010 05:03 |
Last Modified: | 19 Sep 2010 05:50 |
URI: | http://eprints.iisc.ac.in/id/eprint/24366 |
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