Thiagarajan, R and Nandi, US and Kalpagam, V (1982) Mixed ligand complexes in vinyl polymerization-II: [NN′-ethylenebis(salicylideneiminato)] (benzoylacetonato)cobalt(III) as an initiator. In: European Polymer Journal, 18 (3). 261 -264.
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Abstract
The polymerization of methyl methacrylate initiated by a mixed ligand complex. [NN′-ethylenebis(salicylideneiminato)](benzoylacetonato)cobalt(III) has been studied in bulk and in benzene at 70° and 80°. The rate of polymerization is proportional to (concentration of the chelate)1/2 and the monomer exponent is close to 1.5. The activation energy and the kinetic and transfer constants are evaluated. A free radical mechanism has been proposed.
| Item Type: | Journal Article |
|---|---|
| Publication: | European Polymer Journal |
| Publisher: | Elsevier Science |
| Additional Information: | Copyright of this article belongs to Elsevier Publisher. |
| Department/Centre: | Division of Chemical Sciences > Inorganic & Physical Chemistry |
| Date Deposited: | 15 Dec 2009 07:18 |
| Last Modified: | 19 Sep 2010 05:45 |
| URI: | http://eprints.iisc.ac.in/id/eprint/23374 |
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