Malini, R and Krishnan, V (1980) Intermolecular charge-transfer complexes of macrocyclic polyethers with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone. In: Journal of Physical Chemistry, 84 (5). pp. 551-555.
PDF
fulltext.pdf - Published Version Restricted to Registered users only Download (586kB) | Request a copy |
Official URL: http://pubs.acs.org/doi/abs/10.1021/j100442a022
Abstract
The interactions of benzo-15-crown-5, dibenzo-18-crown-6, and dibenzo-24-crown-8 with 2,3-dichloro-5,6-dicyano- 1,4-benzoquinone have been studied in methylene chloride by using spectroscopic methods. These crown ethers from 1:l molecular complexes with the acceptor. The magnitudes of association constants and thermodynamic parameters of complexation are indicative of cooperative interaction of oxygens with the acceptor.
Item Type: | Journal Article |
---|---|
Publication: | Journal of Physical Chemistry |
Publisher: | American Chemical Society |
Additional Information: | Copyright of this article belongs to American Chemical Society. |
Department/Centre: | Division of Chemical Sciences > Inorganic & Physical Chemistry |
Date Deposited: | 02 Feb 2010 10:18 |
Last Modified: | 19 Sep 2010 05:44 |
URI: | http://eprints.iisc.ac.in/id/eprint/22958 |
Actions (login required)
View Item |