Conformation of some N,N'-arylalkyl thioureas by 1H-NMR and infrared spectral analysis

Sudha, LV and Sathyanarayana, DN (1984) Conformation of some N,N'-arylalkyl thioureas by 1H-NMR and infrared spectral analysis. In: Spectrochimica Acta Part A: Molecular Spectroscopy, 40 (8). pp. 751-755.

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Abstract

Several N,N-²-arylalkyl thioureas were examined with 1H-NMR and i.r. spectra in order to study the conformation of the -NHCSNH- group. The influence of temperature and substituents on the chemical shift of the N---H protons has been investigated. Formation of a strong intramolecular hydrogen bond stabilizes the trans-cis conformation for most systems, while for the others the prevalence of different rotational isomers can be postulated. The influence of the steric effect on hydrogen bonding and molecular conformation is discussed.

Item Type:	Journal Article
Publication:	Spectrochimica Acta Part A: Molecular Spectroscopy
Publisher:	Elsevier science
Additional Information:	Copyright for this article belongs to Elsevier science.
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	22 Jul 2009 06:24
Last Modified:	19 Sep 2010 05:38
URI:	http://eprints.iisc.ac.in/id/eprint/21679

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