Evolution of three-dimensional character across the Lan+1NinO3n+1 homologous series with increase in n1

Ram, Mohan RA and Ganapathi, L and Ganguly, P and Rao, CNR (1986) Evolution of three-dimensional character across the Lan+1NinO3n+1 homologous series with increase in n1. In: Journal of Solid State Chemistry, 63 (2). pp. 139-147.

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Abstract

Electrical and magnetic properties of La3Ni2O7 and La4Ni3O10 have been investigated in comparison with those of La2NiO4, LaNiO3, and LaSrNiO4. The results suggest an increasing 3-dimensional character across the homologous series Lan+1NinO3n+1 with increase in n. Accordingly, the electrical resistivity decreases in the order La3Ni2O7, La4Ni3O10, and LaNiO3 and this trend is suggested to be related to the percolation threshold. Magnetic properties of these oxides also show some interesting trends across the series.

Item Type:	Journal Article
Publication:	Journal of Solid State Chemistry
Publisher:	Elsevier Science
Additional Information:	Copyright of this article belongs to Elsevier Science.
Department/Centre:	Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited:	17 Jul 2009 11:13
Last Modified:	19 Sep 2010 05:36
URI:	http://eprints.iisc.ac.in/id/eprint/21239

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