Swathi, RS and Sebastian, KL (2009) Long range resonance energy transfer from a dye molecule to graphene has (distance)-4 dependence. In: Journal Of Chemical Physics, 130 (8). 086101-1.
PDF
4.pdf - Published Version Restricted to Registered users only Download (121kB) | Request a copy |
Abstract
In our previous report on resonance energy transfer from a dye molecule to graphene [J. Chem. Phys.129, 054703 (2008)], we had derived an expression for the rate of energy transfer from a dye to graphene. An integral in the expression for the rate was evaluated approximately. We found a Yuwaka-type dependence of the rate on the distance. We now present an exact evaluation of the integral involved, leading to very interesting results. For short distances (z < 20 A), the present rate and the previous rate are in good agreement. For larger distances, the rate is found to have a z(-4) dependence on the distance, exactly. Thus we predict that for the case of pyrene on graphene, it is possible to observe fluorescence quenching up to a distance of 300 A. This is in sharp contrast to the traditional fluorescence resonance energy transfer where the quenching is observable only up to 100 A.
Item Type: | Journal Article |
---|---|
Publication: | Journal Of Chemical Physics |
Publisher: | American Institute of Physics |
Additional Information: | Copyright of this article belongs to American Institute of Physics. |
Keywords: | dyes;fluorescence;graphene;molecule-surface impact;radiation quenching. |
Department/Centre: | Division of Chemical Sciences > Inorganic & Physical Chemistry |
Date Deposited: | 04 Sep 2009 04:25 |
Last Modified: | 19 Sep 2010 05:29 |
URI: | http://eprints.iisc.ac.in/id/eprint/19563 |
Actions (login required)
View Item |