Enantioselective First Total Syntheses of 2-(Formylamino)trachyopsane and ent-2-(Isocyano)trachyopsane via a Biomimetic Approach

Srikrishna, A and Ravi, G and Subbaiah, Venkata DRC (2009) Enantioselective First Total Syntheses of 2-(Formylamino)trachyopsane and ent-2-(Isocyano)trachyopsane via a Biomimetic Approach. In: Synlett (1). pp. 32-34.

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Abstract

A biomimetic rearrangement of an isotwistane to a tricyclo[4.3.1.0(3,8)]decane has been employed as the key step for the enantioselective first total syntheses of the marine sesquiterpenes 2-(formylamino)trachyopsane and ent-2-(isocyano)trachyopsanes ascertaining the biogenetic relationship between the marine sesquiterpenes neopupukeananes and trachyopsanes.

Item Type:	Journal Article
Publication:	Synlett
Publisher:	Georg Thieme Verlag Stuttgart
Additional Information:	Copyright of this article belongs to Georg Thieme Verlag Stuttgart.
Keywords:	natural products; marine sesquiterpenes; enantioselective synthesis; biomimetic synthesis; acid-catalysed rearrangement
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	11 Jun 2010 08:23
Last Modified:	19 Sep 2010 05:25
URI:	http://eprints.iisc.ac.in/id/eprint/18801

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